| 학회 |
한국화학공학회 |
| 학술대회 |
2000년 봄 (04/21 ~ 04/22, 한양대학교) |
| 권호 |
6권 1호, p.649 |
| 발표분야 |
열역학 |
| 제목 |
Dendrimer 용액상의 기액 상평형: 분자 주위의 다수의 말단기의 영향 |
| 초록 |
We propose a molecular thermodynamic framework to describe vapor-liquid equilibria (VLE) of dendrimer solutions. We examined VLE of dendrimer solutions (polyamidoamine dendrimer/methanol and benzyl dodecyl dendrimer/toluene systems) on the effects of a branched structure and specific interaction formations among endgroups of dendrimer and solvent molecules. The solvent-endgroup specific interaction dominates VLE of given systems. The end-groups of dendrimer also play a great role in determining VLE of highly branched polymer structure. Excellent fits were obtained for VLE data of dendrimer/solvent systems
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| 저자 |
장정규, 배영찬
|
| 소속 |
한양대 |
| 키워드 |
Lattice Cluster Theory; Vapor-Liquid Equilibria; Specific Interaction; Dendrimer
|
| E-Mail |
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| 원문파일 |
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