화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.1366
발표분야 공정시스템 (Process Systems Engineering)
제목 Crystal growth and nucleation kinetics estimation from an unseeded crystallization equation
초록 An equation which is developed for unseeded crystallization without aggregation and breakage is applied to estimation of crystal growth and nucleation kinetics. By solving the conservation of mass and the growth kinetic of particles, the equations about the average size of particles can be derived as a function of time. From the conservation of mass, the nucleation kinetics is dependent of both growth kinetics and the supersaturation.
Total mass and average size of crystals with particle synthesis experiments as a function of time are measured. Nucleation and growth kinetics, induction time and size of nucleus can be estimated by comparing experimental results with numerical solutions of the equation, without solving population balance equation and acquiring crystal size distibution data. The equation can be applied to any unseeded crystallization processes, regardless of types of materials such as ionic, organic, and metalic particle.
저자 김승환1, 양대륙1, 장지웅2
소속 1고려대, 2금오공과대
키워드 공정모델링; 공정최적화
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