| 학회 |
한국공업화학회 |
| 학술대회 |
2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터) |
| 권호 |
15권 1호 |
| 발표분야 |
정밀화학 |
| 제목 |
An improved synthetic procedure for the unsubstitued pentaazatetraoxotricycloundecane skeleton |
| 초록 |
We have studied the synthesis of pentaazatetraoxotricycloundecane (PATOTU) as a basic molecular skeleton for novel high explosive materials because the propellane structure would have high potential energy owing to the symmetric and strained structure but be quite stable. We have previously reported for the first time the successful synthesis of the unsubstituted PAPOTU skeleton. Herein, we present a simple and improved procedure for the unsubstitued PATOTU skeleton. In addition, more readily available diethyl tartrate was used as a starting material instead of expensive dihydroxyfumaricacid. An X-ray analysis result of the target compound will be also shown. |
| 저자 |
이혜령1, 신문용1, 김진석2, 정규현3, 김영규1
|
| 소속 |
1서울대, 2국방과학(연), 3인하대 |
| 키워드 |
PATOTU; azopropellane
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| E-Mail |
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