화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 기능성 고분자
제목 Tuning of Carrier Concentration in Organic Semiconductors Using Self-Assembled Monolayers for Enhanced Thermoelectric Efficiency
초록 Organic conductive polymers (CPs) are good candidates for thermoelectric (TE) materials due to their low thermal conductivity, lightweight, simple processability, and environmentally-friendly characteristics. Among numerous CPs, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) would be the promising candidate TE material due to its advantages of high electrical conductivity, low thermal conductivity, light-weight, and high flexibility. Nevertheless, CPs-based TE materials still suffer from much lower Seebeck coefficients compared with inorganic TE materials. In this work, we successfully demonstrate that the Seebeck coefficient of PEDOT:PSS is enhanced by controlling the hole carrier concentration of PEDOT:PSS using a self-assembly monolayer (SAM). The power factor of the PEDOT:PSS film is about 3 times enhanced. This work can contribute to fabrication of organic-based flexible and high-performance TE modules.f
저자 김진백, 최수영
소속 한국과학기술원
키워드 Self-Assembled Monolayers; Thermoelectrics
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