화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터)
권호 16권 2호, p.1618
발표분야 에너지
제목 Role of graphene as a catalyst support indirect liquid fuel cells
초록 Highly dispersed and stable Pt and Pd on graphene nanosheets (GNS) catalysts were synthesized via a colloidal method using graphene oxide formed by chemical exfoliation. GNS can provide an efficient 2-D planar structure where metal nanoparticles may be able to deposit with maximum utilization so that particle size control and its distribution on GNS are more favorable compared to commercially available carbon black, especially Vulcan-XC. Even in case of more than 60% Pd, homogenous deposition is readily achievable in conjunction with smaller particle size. However, due to the morphological characteristics of graphene oxide or the formation of larger catalysts aggregate, superior electrocatalytic activity cannot be obtained. An important advantage of this catalyst support is to provide strong metal-support interaction, thereby increasing catalyst stability of Pd catalyst for formic acid oxidation.
저자 엄성현1, 주지용2, 전홍래1, 이재영3
소속 1광주과학기술원, 2Ertl center for Electrochemistry and Catalysis, 3Electrochemical Reaction & Technology Laboratory
키워드 Graphene; catalyst support; small organic molecule oxidation; direct liquid fuel cell
E-Mail
원문파일 초록 보기