화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 고분자 합성
제목 Study on the Poly L-lactide(PLLA) and Poly D-lactide(PDLA) prepared by Lactide using Tin(Ⅱ) octoate and lauryl alcohol as a catalyst and initiator.
초록 In recent years, the interest in renewable resource-based materials and biopolymers increases. A polylactide(PLA) is renewable, degradable aliphatic polyester prepared by ring opening polymerization of lactide that is cyclic dimer produced from the dehydration of lactic acid made from fermentation of corn starch. Lactide has two types of isomers such as L-lactide and D-lactide. In this work, polymers were synthesized by ring opening polymerization of lactide as a monomer using Tin(Ⅱ) octoate and lauryl alcohol as a catalyst and initiator, changing amount of initiator, reaction time and reaction temperature. And properties of blends of poly(L-lactide)(PLLA) and poly(D-lactide)(PDLA), and non-blend PLLA, PDLA were characterized, respectively, using GPC, 1H NMR, DSC, XRD.
저자 김지현, 제갈종건, 송봉근
소속 한국화학(연)
키워드 PLLA; PDLA; polymerization
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