화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 고분자합성
제목 Synthesis and characterization of highly stretchable polyrotaxane based polyurethane
초록 Highly stretchable polymer have getting much attention because of their unique properties. In this study, a highly stretchable polymer was synthesized by crosslinking polyurethane with pre-synthesized polyrotaxane from polypropylene glycol (PPG) with low covered cyclodextrin (CD) which acts as both chain extender and crosslinker. One pot method was used to synthesize polyrotaxane by threading beta cyclodextrin (β-CD) along the axis of PPG-tetra amine polymer backbone followed end capped with 2,4,6-trinitrobenzene sulfonic acid (TNBSA). The synthesized polyurethane and polyrotaxane were characterized by HNMR and FTIR spectroscopies. Coverage of polyrotaxane was adjusted by mole ratio of PPG and β-CD. This novel properties of the polymer can vastly covered different applications with flexible surface for wearable device.
저자 곽수민, 정일두, Md Hasan Truabee
소속 부산대
키워드 cyclodextrin; polyrotaxane; polyurethane
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