화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터)
권호 42권 2호
발표분야 기능성 고분자
제목 Flexible and Robust Superomniphobic Surfaces Created by Localized Photofluidization of Azopolymer Pillars
초록 Springtails possess robust omniphobic skins with nanotextures with a doubly re-entrant geometry(DRG). Although omniphobic surfaces are promising for various applications, it remains an important challenge to mimic the structural feature of springtails. This paper presents a pragmatic method to create DRG and robust super-omniphobic surfaces by exploiting localized photofluidization of azopolymers. Irradiation of circularly-polarized light reconfigures azopolymer micropillars to have a mushroom-like head with a DRG through protrusion and inward bending of polymer film from the top edge. The geometry exhibits super-omniphobicity even for liquids whose equilibrium contact angles are almost zero in the presence of a practical level of external pressure. The simple fabrication process is highly reproducible, scalable, and compatible with various substrates. Our results suggest that our photofluidization technology will provide a practical route to create robust super-omniphobic surfaces.
저자 최재호1, 김희탁2, 김신현2, 조원희2
소속 1KAIST, 2생명화학공학과
키워드 Superomniphobic; doubly re-entrant geometry; localized photofluidization; azopolymer; micro/nanopatterning
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