| 학회 | 한국고분자학회 |
| 학술대회 | 2002년 가을 (10/11 ~ 10/12, 군산대학교) |
| 권호 | 27권 2호, p.114 |
| 발표분야 | 고분자 가공/블렌드 |
| 제목 | Reaction kinetics and morphological changes at polymer-polymer interface |
| 초록 | The reaction kinetics and interfacial roughness are important to characterize the interface between two immiscible blends with a reactive compatibilizer. However, a few studies on reaction kinetics and interfacial roughness are available. In this study, we interpret the reaction kinetics by correlating interfacial roughness with rheological properties. A blend system (PS-mCOOH/PMMA-GMA) was used to prepare two plates of each polymer by compression molding on silicon wafer for smooth surface. Rheological properties were obtained from the two plates welding together in rheometer at different temperatures. The modulus change showed three different stages in reaction kinetics. The interface of each stage was investigated with AFM and TEM. From our results, the three stages are considered to have reaction-controlled stage, interface broadening, and micelle formation stage. This work was supported by Applied Rheology Center governed by KOSEF. |
| 저자 | 김황용, 정운용, 김진곤 |
| 소속 | 포항공대 화공과 |
| 키워드 | blend; interface; viscoelasticity; reactive blend; mechanical shear |
