| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터) |
| 권호 |
17권 2호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Ring structures embedded highly active plasticizers capable of bonding with energetic binders through Cu-free azide-alkyne click chemistry |
| 초록 |
Ring structures embedded highly active plasticizers (RSEHAPs) containing an activated terminal acetylene moiety are synthesized by esterification and designed by introducing ring structures instead of traditional energetic groups since cyclic alkyl compounds are expected to be a potential energy resource. RSEHAPs are found to work properly as a general plasticizer in GAP-based polyurethane (PU) formulation process and then complete the click reaction under Cu-free condition with azide groups of GAP prepolymer in PU curing process. Aiming at exhibiting a promising plasticization and high reactivities to prepolymers in PU curing reaction, structural diversity of RSEHAPs on the plasticization effect to prepolymers and thermodynamic study of click reaction with prepolymers are investigated in detail. |
| 저자 |
MA MINGYANG1, 권영환1, 김진석2, 장승현1
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| 소속 |
1대구대, 2국방과학(연) |
| 키워드 |
RSEHAPs; “click” reaction; catalyst-free; PU formulation
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| E-Mail |
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