화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터)
권호 35권 1호
발표분야 고분자 합성
제목 Intercalation of hyperbranched polyglycidol and tri-block derivative within Na+-montmorillonite
초록 Hyperbranched macromolecules has attained increasing interest as it is a potential alternative for the perfectly branched dendrimers that have to be constructed in a usually tedious, stepwise approach. We have synthesized different molecular weight hyperbranched poly-glycidols (HBP), and have studied its intercalation in Na+-montmorillonite clay. HBP was polymerized using trimethylolpropane and PEG as the initiator by ring opening polymerization. These polymer were characterized by NMR, GPC and SLS. Intercalation of HBP into montmorillonite was carried out by sonication in water. The distance between the two layers was changed by different molecular weight HBP. The result of IR, TGA and X-ray diffraction studies support this investigation.
저자 조정규1, 하창식2, 김일1
소속 1부산대, 2합성고분자 생물접합 하이브리드 재료 사업단
키워드 hyperbranched; polyglycidol; montmorillonite; intercalation
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