학회 |
한국화학공학회 |
학술대회 |
2012년 가을 (10/24 ~ 10/26, 부산 BEXCO) |
권호 |
18권 2호, p.2499 |
발표분야 |
촉매 및 반응공학 |
제목 |
Fischer-Tropsch synthesis on alumina coated Co/SiC catalysts |
초록 |
Cobalt-based Fischer-Tropsch Synthesis (FTS) catalysts have been variously modified to get a high catalytic activity and to produce high molecular weight hydrocarbons. In the present study, we have studied FTS reaction on the cobalt-supported alumina-modified SiC support which was obtained by sol-gel method. The SiC support was previously modified using 1wt%TEOS through dry impregnation method, and alumina was subsequently introduced by sol-gel method using aluminum isopropoxide precursor with the weight percentage of Al2O3/SiC from 0 to 20%. The 15wt%Co was impregnated on the alumina-modified SiC support, and 20wt%Al2O3-modified Co/Al2O3-SiC was found to show a superior catalytic performance to other catalysts. The different catalytic performances on Co/Al2O3-SiC catalysts were further investigated by using BET, XRD, TPR and chemisorption analysis. |
저자 |
구현모1, 유동원1, 이발상2, 박명준2, 배종욱1
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소속 |
1성균관대, 2아주대 |
키워드 |
Fischer-Tropsch synthesis; silicon carbide; sol-gel method; γ-alumina; cobalt-based catalyst
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E-Mail |
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원문파일 |
초록 보기 |