화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 가을 (10/24 ~ 10/26, 부산 BEXCO)
권호 18권 2호, p.2499
발표분야 촉매 및 반응공학
제목 Fischer-Tropsch synthesis on alumina coated Co/SiC catalysts
초록 Cobalt-based Fischer-Tropsch Synthesis (FTS) catalysts have been variously modified to get a high catalytic activity and to produce high molecular weight hydrocarbons. In the present study, we have studied FTS reaction on the cobalt-supported alumina-modified SiC support which was obtained by sol-gel method. The SiC support was previously modified using 1wt%TEOS through dry impregnation method, and alumina was subsequently introduced by sol-gel method using aluminum isopropoxide precursor with the weight percentage of Al2O3/SiC from 0 to 20%. The 15wt%Co was impregnated on the alumina-modified SiC support, and 20wt%Al2O3-modified Co/Al2O3-SiC was found to show a superior catalytic performance to other catalysts. The different catalytic performances on Co/Al2O3-SiC catalysts were further investigated by using BET, XRD, TPR and chemisorption analysis.
저자 구현모1, 유동원1, 이발상2, 박명준2, 배종욱1
소속 1성균관대, 2아주대
키워드 Fischer-Tropsch synthesis; silicon carbide; sol-gel method; γ-alumina; cobalt-based catalyst
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