| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 |
21권 2호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Two electron mediators generation concurrently at MFI-type zeolite membrane divided tubular cell: An electrolysis study |
| 초록 |
The robustness and high volumetric conversion performance of tubular electrochemical reactor was disclosed to generate a single mediator in our recent publiation. In the present investigation, two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- have been generated using a tubular MFI-type zeolite coated membrane divided electrochemical cell via paired electrolysis. The electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved in highly acid and highly base pHs respectively. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement. At the same time no migration of Co(II) or [Ni(II)(CN)4]2- were observed and additional results will be discussed finally. |
| 저자 |
G. MUTHURAMAN, A.G. Ramu, 문일식
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| 소속 |
순천대 |
| 키워드 |
Zeolite tubular membrane; tubular electrochemical cell; two mediator generation; paired electrolysis
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| E-Mail |
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