| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO)) |
| 권호 |
25권 2호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Fully Degradable n-Type Organic Semiconductors for High-Performance and Transient Organic Electronics |
| 초록 |
The degradable organic semiconductors have significant potentials for the transient and biomedical organic electronics, but there have been only few studies of fully-degradable conjugated polymers (CPs). In addition, these examples are limited to p-type CPs. Herein, we develop a series of n-type fully-degradable CPs, naphthalene diimide (NDI)-based terpolymer (PNDIT2/IM-x). The incorporation of imine linker (IM) into the conjugated backbone of NDI affords the capability of hydrolysis degradation while maintaining efficient π-conjugations. Additional benefit of this molecular design is tunability of the degradation and electrical characteristics depending on IM content (x). At the optimal point, the transient organic field effect transistor (OFETs) of PNDIT2/IM-0.45 exhibits a high mobility (µe) of 0.04 cm2 V-1S-1 and demonstrates fully degradations under acidic conditions. High µe value is attributed to the enlarged edge-on orientations with very tight stackings. |
| 저자 |
김진우1, 박현정1, 김영권1, 김동욱2, 김선주2, 김범준1
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| 소속 |
1KAIST, 2중앙대 |
| 키워드 |
fully degradable conjugated polymer; n-type semiconductor; transient organic electronics; n-type OFET; naphthalene diimide-based terpolymer; degradability
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| E-Mail |
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