화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-에너지저장·변환
제목 Improvement in power conversion efficiency of dye-sensitized solar cells with sodium sulfide-modified photoanodes
초록 TiO2 films on transparent electrodes were modified with an aqueous sodium sulfide solution, and the resulting films were applied to photoanodes of dye-sensitized solar cells (DSSCs). The sodium sulfide modification by a simple dipping method enhanced the power conversion efficiency of DSSC, mainly due to an improvement in the open-circuit voltage (Voc). By monitoring UV-visible absorbance spectra, UPS valence band spectra and dark currents, we could attribute the increase in the Voc to a negative shift of TiO2 conduction band edge, resulting from the formation of anions on the TiO2 surface by the modification. *Acknowledgements: This work is financially supported by the Ministry of Education, Science and Technology (MEST) through the fostering project of Industrial Complex Campus.
저자 이연주1, 성혜경2, 서종성3, 이도경1, 한윤수1
소속 1대구가톨릭대, 2부산대, 3(주)솔라팜
키워드 dye-sensitized solar cell; surface modification; sodium sulfide; negative shift of conduction band edge.
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