화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 고분자가공/복합재료- 미래 자동차용 고분자소재 최신기술 동향
제목 Systematical preparation of modified grapheme quantum dot (GQD) with tunable surface property
초록 Systematic control of surface chemistry of graphene quantum dots (GQDs) is extremely challenging and is one of the key technologies for applying GQDs into practical use. Here we prepared surface modified GQDs with direct bonding of small molecule on GQDs. It is observed that surface property of GQDs systematically controlled depending on the amount of small molecule on GQD. Among the samples, the GQD treated with excess amount of small molecule showed highly hydrophobic property. In addition, modified GQDs can behave like both a molecular and a colloidal surfactant. In specific, surface modified GQD is capable of stabilizing Pickering emulsions of organic solvents in oil/water system and can also act as a molecular surfactant to disperse insoluble materials in water. Finally, surface modified GQDs are successfully applied as surfactant in emulsion polymerization. The ease of control of surface chemistry may offer great potential application in all system using surfactant.
저자 조한희1, 양현승2, 강동진3, 김범준3
소속 1KAIST, 2KAIST 생명화학공학과, 3KAIST 생명화학공학과
키워드 graphene quantum dot; surface chemistry
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