| 학회 |
한국고분자학회 |
| 학술대회 |
2005년 가을 (10/13 ~ 10/14, 제주 ICC) |
| 권호 |
30권 2호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Crosslinked Organic-Inorganic Hybrid Hole Injection Polymer for Organic Light Emitting Diodes |
| 초록 |
The integrity of interfacial contact between inorganic indium tin oxide (ITO) anode and organic emitting layer is crucial to the performance in organic light emitting diodes (OLED). In order to overcome the deficiencies of currently applied material PEDOT:PSS, we have synthesized a thermally crosslinkable organic-inorganic hybrid hole injection polymer, containing N, N’-bis[4-{3-(triethoxysilyl)propylcarbamato}methyloxyphenyl]-N-4-butylphenylamine (TPA) and N,N’-bis(4-n-butylpheny)-N,N’-bis[4-{3-(triethoxysilyl)propylcarbamato}methyloxyphenyl]-1,1’-biphenyl-4,4’-diamine (TPD). Soluble prepolymer was prepared to fabricate insoluble hole injection layer (HIL) via spin-coating followed by thermal crosslinking of ethoxysilane moieties. Soluble prepolymers with moderate molecular weights rendered defect-free films and exhibited good adhesion property between inorganic anode and organic emitting layer. OLED’s prepared with these hybrid HIL polymers showed improved device efficiency, as compared with those using PEDOT:PSS. |
| 저자 |
장도영1, 임윤희1, Daniel Kessler2, 김주현3, 윤도영4
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| 소속 |
1서울대, 2Institute of Organic Chemistry, 3Univ. of Mainz, 4Germany |
| 키워드 |
hole injection material; triphenyldiamine; triphenyldiamine; organic-inorganic hybrid; polysilsesquioxane
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| E-Mail |
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