화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2021년 봄 (04/21 ~ 04/23, 부산 BEXCO)
권호 27권 1호, p.682
발표분야 에너지 환경
제목 Architecture of Mo:BIVO4/Graphene Photoanode: A Versatile Hybrid System for Enhanced Photoelectrochemical Water Splitting
초록 Bismuth vanadate (BiVO4) is an attractive and efficient photoanode for photoelectrochemical (PEC) water splitting due to excellent visible light activity and good photo-chemical stability. However, due to poor charge separation and low charge carrier mobility hinder the improvement of PEC performance of BiVO4. Though, graphene has been demonstrated as active co-catalysts and photosensitizers to facilitate surface water oxidation kinetics. Therefore, to improve the overall efficiency we propose three component system Mo:BiVO4/graphene hybrid composites. First, BiVO4 and Mo:BiVO4/Graphene nanostructures has been prepared by hydrothermal method. The Mo metal content and reaction parameters of films have been optimized to obtain a high surface area, porous and uniform nanostructures. XRD shows the phases of Mo:BiVO4/graphene hybrid composites and FE-SEM and TEM data reveled strong interface between Mo:BiVO4 and graphene. The pristine material with graphene incorporation, showed an excellent photocatalytic activity under natural sunlight. Therefore, the developed material is a promising candidate for potential photocatalysis applications.
저자 Tamboli Mohaseen, Asiya M. Tamboli, 바수데바레디, 김보명, 박진호
소속 영남대
키워드 에너지
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