화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 분자전자 부문위원회
제목 Synthesis and characterization of low band gap polymers based on 3,6-Bis-(5-bromo-thiophen-2-yl)-2,5-bis-(2-octyl-dodecyl)-2,5-dihydro-pyrrolo[3,4-c]pyrrole-1,4-dione(DPP) as acceptor in polymer photovoltaic cells
초록 Nowaday, there are many researches focus on finding new energy sources since fossil fuel will be increasingly depleted. Polymer solar cells (PSCs) are one of prospective candidates for alternative energy source. Diketopyrrolopyrrole (DPP) as an acceptor unit is well-known for a promising material in organic electronic devices because DPP is a strong acceptor with a fused ring type for coplanarity and decreasing -stacking and incorporating fused aromatic ring moieties, the crystallinity of this type of materials can be well controlled by choosing suitable solvents or thermal annealing, leading to desired film morphologies. Herein we synthesize polymers with donor–acceptor (D–A) concept based on alkly-9H-carbazol(CZ) or alkly-9,10-phenanthren(PN) and 2,5-Dioctyl-3,6-di-thiophen-2-yl-2,5-dihydro-pyrrolo[3,4-c]pyrrole-1,4-dione(DPP) by Suzuki coupling copolymerization. In this presentation, we will report the synthesis method, optical and photovoltaic properties of the polymer.
저자 배준휘, 임경은, 김주현
소속 부경대
키워드 DPP; solar cells; phenanthrene; carbazole
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