화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터)
권호 17권 2호
발표분야 포스터-나노
제목 Controllable Fabrication of Silica/Titania Core/Shell Structure as Light Scattering Materials for Dye-Sensitized Solar Cells
초록 A simple strategy is presented to add light-scattering materials (LSMs) into photoanode for light-harvesting in dye-sensitized solar cells (DSSCs). Silica/Titania core/shell nanoparticles (STCS-NPs) with various diameters (110, 240, and 530 nm) were synthesized as LSMs for investigating the influence of the size and refractive index of light-scattering particles on light scattering properties. The optical properties of STCS-NPs were evaluated and compared with those of silica nanoparticles and titania nanoparticles. STCS-NPs, consisting of a high refractive index shell and a low refractive index core, lead to optical confinement in photoanode film, resulting in strong light scattering efficiency. As the result, DSSCs exhibited an enhanced power conversion efficiency of 7.9% in comparison with the 6.5% for a conventional photoelectrodes made of titania nanoparticles.
저자 윤주영, 손수임, 황선혜, 장정식
소속 서울대
키워드 SiO2/TiO2 core/shell nanoparticles; light scattering; Mie scattering; dye-sensitized
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