| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 가을 (11/12 ~ 11/14, ICC 제주) |
| 권호 |
12권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Selective Polymorph Crystallization of Glycineon Nanopatterned Polymer Surfaces |
| 초록 |
The poly (styrene-b-ethylene oxide) (PS-b-PEO) patterned substrates having ordered cylindrical PEO domains of 20-30 nm were served as nucleation sites and were utilized to control the size of the crystals. The hydrophilic characteristics of the PEO domain can provide the driving force to position hydrophilic particles selectively within the patterned domain. Under a well-defined condition, glycine nanoparticles were selectively positioned within hydrophilic PEO nanodomains. Additionally nanocrystals grown on nanopatterned surfaces might lead to formation of high energy metastable polymorphs. To study the polymorphic outcome of glycine constrained on patterned substrates, crystals obtained on a patterned substrate and on a bare silicon wafer were characterized by Raman spectrometer and AFM. |
| 저자 |
이민경1, 이종휘1, 방준하2
|
| 소속 |
1중앙대, 2고려대 |
| 키워드 |
polymorph; PS-PEO; nanopatterned surface; Glycine
|
| E-Mail |
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