| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Flower micelles from block copolymer poly( 2-(4-vinylphenyl)pyridine)-b-poly(2-vinyl)pyridine) |
| 초록 |
The novel block copolymer, poly(2-(4-vinylphenyl)pyridine)-b-poly(2-vinylpyridine) (PP2VP-b-P2VP) was synthesized by living anionic polymerization technique. Aggregation behavior of the (PP2VP-b-P2VP) block copolymer was studied in a selective solvent methanol, which is more favorable for the P2VP than PP2VP block. Introduction of the phenyl group between vinyl back bone and pyridine produce polarity difference between PP2VP and P2VP block in methanol which leads to the formation of a 40 ± 1 nm mono-dispersed micelles. Morphological studies of the micelles were carried out by using scanning electron microscope (SEM) and transmission electron microscope (TEM). TEM micrographs of the micelles clearly deciphered flower type shape of the micelles. |
| 저자 |
강남구, Mohammad Changez, 이재석
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| 소속 |
광주과학기술원 |
| 키워드 |
Flower micelles; block copolymer; living anionic polymerization
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| E-Mail |
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