화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2011년 가을 (10/26 ~ 10/28, 송도컨벤시아)
권호 17권 2호, p.1183
발표분야 고분자
제목 Fabrication of Dye-sensitized Solar Cells using Polycarbonate Membranes Templated TiO2 Nanowires/Nanotubes
초록 Different diameter TiO2 Nanowires/Nanotubes (TNW/TNT) arefabricated by soft template-based synthesis technique. Track-etched polycarbonate (PC) was used as template to synthesize TNW/TNT films which used as interfacial layer to improve the efficiency of dye-sensitized solar cell (DSSC). Upon calcination at 500oC, TiO2 nanowires (15TNW) were obtained from PC with a 15 nm pore diameter, whereas TiO2 nanotubes (50TNT and 100TNT) were generated from PC with 50 and 100 nm diameter pores, respectively. TNW and TNT were used as photoelectrodes in DSSCs employing a polymer electrolyte. These TNW and TNT films were further coated with the graft copolymer-directed mesoporous TiO2 and were used as interfacial layers between the FTO glass and the 4-μm-thick nanocrystalline TiO2 film. The DSSC performance was systematically investigated in terms of interfacial resistance and charge recombination using electrochemical impedance spectroscopy.
저자 고주환, 노동규, 김상진, Rajkumar Patel, 김종학
소속 연세대
키워드
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