학회 | 한국화학공학회 |
학술대회 | 2007년 봄 (04/19 ~ 04/20, 울산 롯데호텔) |
권호 | 13권 1호, p.625 |
발표분야 | 에너지/환경 |
제목 | Study of kinetics of PET (polyethylene terephthalate) depolymerization in supercritical methanol |
초록 | Polyethylene terephthalate (PET) is a thermoplastic polymer resin of the polyester family used in synthetic fibers, liquid containers, thermoforming applications and engineering resins. With extensive use of PET in various applications, its recycling has received wide attention for the preservation of resources and the protection of the environment. One of the recycling processes is to depolymerize PET into its monomer products. For the efficient design of PET depolymerization, a robust kinetic model of PET depolymerization is strongly needed. In this study, we consider methanoysis process of PET using supercritical methanol. Theoretical kinetics model was developed employing concepts of continuous kinetics. Kinetic equations were developed for thermal degradation of PET and the governing differential equations were solved using moment method. The theoretical model is expected to predict the experimental data. |
저자 | 임 란1, 김도현1, 한명완2 |
소속 | 1한국과학기술원 / 초미세화학공정시스템연구센터(CUPS), 2충남대 |
키워드 | PET; degradation kinetics; depolymerization process |
원문파일 | 초록 보기 |