화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 봄 (04/29 ~ 05/01, BEXCO (부산))
권호 19권 1호
발표분야 고분자_포스터
제목 Synthesis and electrical properties of novel oligomer semiconductors for OFETs: Asymmetrically end-capped acene-heteroacene conjugated oligomers
초록 Noble small molecules composed of an aromatic phenylene-trithiophene and naphthalene-trithiophene conjugated core were synthesized and examined for their property in p-type OFET devices. The phenylene and naphthalene moieties were combined with a trithiophene to introduce torsional structures into the conjugated core and improve the solubility compared with the solubility of the quaterthiophene core containing molecule. Although phenylene-trithiophene and naphthalene-trithiophene containing molecules showed lower mobilities (2.9 x 10-3 and 1.04 x 10-2 cm2/V, respectively) than quaterthiophene containing molecule (3.21 x 10-2 cm2/V), they showed more film uniformity caused by improved solubility. The thermal stability, photochemical properties, and morphological characteristics were investigated using TGA, DSC, cyclic voltammetry, and XRD techniques.
저자 박광훈1, 백장열1, 박성종1, 강문성1, 김예별2, 박찬언2, 김윤희1
소속 1경상대, 2포항공과대
키워드 OFETs; acene-heteroacene
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