화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2011년 봄 (04/27 ~ 04/29, 창원컨벤션센터)
권호 17권 1호, p.1063
발표분야 환경
제목 Effect of mixture of electrolytes on removal efficiency for VOCs using electrogenerated Co(III) by electro-reactor process
초록 Mixture of electrolyte solutions are growing field in various applications like selectivity and reactivity etc.. The present work describes effect of combination of H2SO4 and HClO4 on removal of volatile organic compounds (VOCs) using electrogenerated Co(III) ion by mediated electrochemical oxidation. Herein, first part deals preparation of suitable composition of H2SO4 and HClO4 and its absorptive behavior on VOCs analyzed by constant current electrolysis. Further, free Co(II) mediator used for mediated electrochemical oxidation (MEO) of mixture electrolyte’s absorbed VOCs at electro-reactor and the absorption effect of VOCs compared by GC peak analysis of oxidation efficiency of VOCs. In separate experiments, absorptive effect of VOCs in mixture of electrolytes correlates with cyclic voltammetry results. This paper will end with a short discussion on adsorptive effect on VOCs.
저자 정상준, 문일식, G. Muthuraman
소속 순천대
키워드 Co(II)/Co(III); 전기화학; 전기산화
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