| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Odd-Even Effects of Alkyl Chain Spacer on the Electrical Performance of Diketopyrrolopyrrole-Based Polymer Semiconductors |
| 초록 |
A series of diketo-pyrrolopyrrole-based polymer semiconductors with branched alkyl groups containing even or odd numbers of linear spacer groups are synthesized to investigate the relationship between molecular structure and electrical properties. To date, however, very little is known about an odd-even effect of alkyl side chains of conjugated polymers due to their relatively disordered or complex conformation compared with small molecules. Herein, odd-even effect of alkyl side-chain length in conjugated polymers on the molecular packing and charge transport characteristics are thoroughly investigated and the optimal side-chain geometries for the most efficient charge transport are determined. Investigation of structure-property relationship in this work can provide new insight into the molecular design of high-performance polymer semiconductors. |
| 저자 |
유호정1, 백장열2, 송인호3, 강일2, 안형주4, 신태주4, 권순기2, 김윤희2, 오준학3
|
| 소속 |
1울산과학기술대, 2경상대, 3포항공과대, 4포항 가속기(연) |
| 키워드 |
odd-even effects; linear spacer groups; alkyl side chains; diketopyrrolopyrroles; organic thin-film transistors
|
| E-Mail |
|
