화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO))
권호 25권 2호
발표분야 포스터-환경·에너지
제목 Titanium Carbide MXenes with Specific Functional Groups as Platinum Supports
초록 MXenes possess attractive high conductivity, and durability for application in electrocatalysis. Tailored Ti3C2 has been actively employed as promising support candidates in Pt-loaded catalytic systems to improve the hydrogen evolution reaction (HER). It is noted that the effect of different surface functional groups, which may play a crucial role to optimize the interaction with loaded Pt nanoparticles, has not been investigated to date. 3D wrinkled Ti3C2(OH)x and Ti3C2Ox were prepared after the alkali-induced process. 3D MXene with high concentration of -F groups (Ti3C2Fx) were prepared by mixing with HF. Distinct electrochemical properties were obtained due to diverse terminations on the surface of Ti3C2. In this work we direct our attention to the effect of these surface functional groups on the resulting interactions with Pt to improve the electrocatalytic activity of Pt-loaded Ti3C2 materials toward HER.
저자 홍혜지1, 김호영2, Filipe Marques Mota1, 조원일2, 김진영2, 김동하1
소속 1이화여자대, 2한국과학기술(연)
키워드 MXene; Pt; Surface engineering; HER; Electrocatalysis
E-Mail