| 학회 |
한국공업화학회 |
| 학술대회 |
2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center)) |
| 권호 |
24권 1호 |
| 발표분야 |
[에너지저장·변환2] 차세대 이차전지 기술개발 동향 |
| 제목 |
NASICON-type NaV2(PO4)3 as a cathode material for calcium-ion batteries |
| 초록 |
The recent discovery of reversible plating and alloying of calcium has invoked considerable interest in calcium-based rechargeable batteries toward overcoming the limitations of conventional Li-ion batteries. Theoretical calculations also suggest that the development of cathode materials is anticipated. However, only a few cathode materials have been tested thus far, and these exhibit low energy-storage capability and poor cyclability. Herein, we report the highly reversible Ca-intercalation capability of NASICON-type NaV2(PO4)3, making it potential cathode material for nonaqueous Ca-ion batteries, with high capacity (90 mAh g−1) and voltage (~3.5 V), and good cyclability. These results demonstrate the feasibility of NaV2(PO4)3, as a highly reversible intercalation-type cathode material for calcium-ion batteries, and unveil the underlying intercalation mechanism. |
| 저자 |
전부식, 허종욱, 형주은, 곽헌호, 이동민, 홍승태
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| 소속 |
대구경북과학기술원 |
| 키워드 |
calcium-ion battery; NASICON; cathode material; intercalation; structure
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| E-Mail |
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