화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 분자전자 부문위원회 I
제목 Facile Synthesis of Stable and Highly Luminescent Methylammonium Lead Halide Nanocrystals for Efficient Light Emitting Devices
초록 Metal halide perovksites are promising candidates for use in light emitting diodes(LEDs), due to their potential for colour tunable and high luminescence efficiency. While recent advances in perovskite-based light emitting diodes have resulted in external quantum efficiencies(EQEs) exceeding 12.4% for the green emitters, and 20% infrared emitters, the EQEs of the red and blue emitters still lag behind. Herein, we report the preparation and characterisation of a highly luminescent and stable suspension of methylammonium lead triiodide(CH3NH3PbI3) perovskite nanocrystals(NCs), where we sytnthesise the nanocrystals via a ligand-assisted reprecipitation technique. Through tuning the conditions,we obtain a solution of CH3NH3PbI3 NCs with a photoluminescence quantum yield exceeding 93% and tunable emission between 660nm and 705nm. We also achieved red emission at 635nm by blending the NCs with bromide salts and obtained perovskite-based LEDs with maximum electroluminescent EQE of 2.75%
저자 이욱희1, 이보람1, 송명훈2
소속 1부경대, 2울산과학기술원
키워드 Perovskite Light Emitting Diodes; metal halide; nanocrystal; methylammonium lead triiodide; high luminescence; stable suspension; tunable emission
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