| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
분자전자 부문위원회 Ⅰ,Ⅱ |
| 제목 |
Molecular Engineering of Donor-Acceptor Organic Dye Sensitizer for Highly Efficient Hybrid CO2 Reduction Catalytic System |
| 초록 |
Based on the molecular design that introduces a non-planar bulky bis-dimethylfluorenyl amino group and benzothiadiazole moiety as electron donor and electron acceptor unit, respectively, we have finely tailored a metal-free organic dye in photocatalytic CO2 reduction system prepared by fixing a dye and a Re(I) complex on TiO2 nanoparticles. In series of dyes, Flu-CNCA-sensitized TiO2/ReP particles exhibited the most efficient CO2 to CO conversion activity (a TONCO of ~1089 for ＞70 h) with 3 vol % H2O in DMF solution; irradiation at λ ＞400 nm. Under irradiation at λ ＞ 500 nm, the hybrid ternary system using π-extended dye showed more than 5 times higher CO2 to CO conversion activity than conventional organic dye. |
| 저자 |
최민수, 이대한, 이상훈, 최성한, 강상욱, 손호진
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| 소속 |
고려대 |
| 키워드 |
Donor-Acceptor Organic dye; Photosensitizer; CO2 reduction
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| E-Mail |
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