화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터)
권호 42권 2호
발표분야 분자전자 부문위원회 I
제목 Enrichment of Semiconducting-SWNTs using Thiophene based Conjugated Polymers with High Alkyl Side-Chain Density for Thin Film Transistors
초록 In the development of post-sorting methods for single-walled carbon nanotubes (SWNTs) with identical electrical property, conjugated polymers (CP) have received significant attention due to their high yield and purity sorting ability. The high purity of semiconducting SWNTs isolated from as-synthesized SWNTs can be one of potential materials in low-cost large-area printed electronics including thin film transistors (TFTs). Many studies demonstrated the ability of a various types of CP such as polyfluorene, but thiophene-based polymers have not been widely investigated to selectively separate a particular chirality of SWNT. Herein, we selectively sort SWNTs using thiophene based CPs with different alkyl chain density via simple centrifugation steps. A high density of polymer shows good sorting ability showing high purity of above 99%. Finally, the fabricated SWNTs based bottom gate-bottom contact TFTs display p-dominant property and the obtained best mobility is 8.69 cm2V−1S−1.
저자 이민혜1, 이승훈2, 김지홍1, 이솔이3, 임대희1, 황경태1, 황한수1, 정용채3, 노용영2, 김동유1
소속 1광주과학기술원, 2동국대, 3한국과학기술(연)
키워드 selective sorting; single-walled carbon nanotubes; conjugated polymers; thin film transistors; alkyl side-chains
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