| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Novel π-Spacer Linked Bis-Benzothiadiazole Blocks for Organic Field-Effect Transistors with Tunable Polarity |
| 초록 |
In general, steric hindrance of the polymer chains results in poor electrical performance in the semiconducting polymer-based organic field-effect transistors (OFETs). Recognizing the importance of the molecular co-planarity and with the aim of developing new, herein we present novel π-spacer linked bis-benzothiadiazole (bis-BT) units with enlarged planarity relative to a conventionally used acceptor, BT. These units have been incorporated into centro-symmetric ketopyrrole cores to facilitate charge transport by enhancing the planarity of the polymer backbones with strong accepting properties. These polymers yield relatively well-balanced ambipolar OFET performances with tunability in the dominant polarity. |
| 저자 |
한아름1, 김종기1, 홍자연2, 김경식1, 이정훈1, 신태주3, 양창덕1, 오준학2
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| 소속 |
1울산과학기술대, 2포항공과대, 3포항가속기센터 |
| 키워드 |
polymer semiconductor; field-effect transistor; polarity
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| E-Mail |
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