화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2005년 봄 (04/14 ~ 04/15, 전경련회관)
권호 30권 1호, p.493
발표분야 분자전자 부문위원회
제목 Synthesis and Characterization of Conducting Polymers in Supercritical CO2
초록 In this study, the usage of supercritical CO2 as a alternative solvent for polymerization was investigated through the characterization of the structure and the solubility of the polymers synthesized in supercritical CO2. Poly(TDFOPP) and poly(DDFHPP) the derivatives of π-conjugated polymers, were synthesized by the introduction of substituents into 4-position of 1,6-heptadiyne. Also poly(URET), the derivative of poly(thiophene) having urethane side group, was synthesized.
In this presentation, polymers were polymerized in supercritical CO2 showed the better solubility behavior than others. This feature can improve the processibility and facilitate the wide application in electric devices, and the supercritical CO2 can be the alternative solvent in polymerization.
저자 황찬구1, 신원석1, 진성호1, 제갈영순2, 임권택3, 황하수3
소속 1부산대, 2경일대, 3부경대
키워드 Conducting Polymer
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