화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 가을 (10/24 ~ 10/26, 부산 BEXCO)
권호 18권 2호, p.1925
발표분야 에너지
제목 First Operational Experience of Slurry Phase Reactor for Fischer-Tropsch Synthesis in 1BPD Scale GTL process
초록 Due to the depletion of petroleum and the newly discovered natural gas resources such as shale gas and coalbed methane, Fischer-Tropsch synthesis (FTS), one of the key technologies in gas-to-liquids (GTL) process, is widely gaining attention as an alternative method to produce environmentally benign oils. To efficiently utilize these resources and independently develop domestic technology, 1 BPD scale GTL pilot was designed, manufactured and has been being operated by Korea GTL consortium. To design a reactor for FTS, a rigorous mathematical model was developed with gProms model and hydrodynamic mock-up test. In addition, a newly-developed high performance KRICT catalyst having high mechanical resistance and hydrothermal stability was used. We have operated the pilot 3 times including trial run, and the cumulative operation time totals 650 h. CO conversion ranged from 65 to 85% and C5+ selectivity ranged from 80 to 85% depending on the operation condition. First operational experience including 6 years development history for GTL process will be discussed.
저자 하경수, 이윤조, 김두일, 곽근재, 박조용, 강석창, 박선주, 전기원
소속 한국화학(연)
키워드 Fischer-Tropsch; Slurry bubble column reactor; cobalt; synthetic fuel; GTL
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