화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 가을 (10/24 ~ 10/25, 한양대학교)
권호 9권 2호, p.1606
발표분야 고분자
제목 A study on the cure kinetics and phase separation of the Epoxy/CTBN-ATPEI-CTBN triblock copolymer/NMA
초록 To improve the toughness of epoxy resin in order to serve high-standard structural and mechanical component applications, carboxyl terminated nitrile rubber (CTBN) - amine terminated polyetherimide(ATPEI) ? CTBN triblock copolymer (ABA type) as an functionalized thermoplastic was introduced. In this study, the cure kinetics of an epoxy system containing the diglycidyl ether of bisphenol A (DGEBA) and nadic methyl anhydride (NMA) as a curing agent, and their blends with ABA triblock copolymer at 20wt% were studied. Also, In the curing process, two major reactions were observed and identified by using a multi-autocatalytic model equation for the cure kinetics.
The co-continuous phase can be obtained in the range of high contents of ABA triblock copolymer(20wt% and 30wt%) at 120℃.
저자 김민영, 이정훈, 황승철, 김원호
소속 부산대
키워드 cure kinetics;phase separation;epoxy
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