학회 | 한국화학공학회 |
학술대회 | 2003년 가을 (10/24 ~ 10/25, 한양대학교) |
권호 | 9권 2호, p.1606 |
발표분야 | 고분자 |
제목 | A study on the cure kinetics and phase separation of the Epoxy/CTBN-ATPEI-CTBN triblock copolymer/NMA |
초록 | To improve the toughness of epoxy resin in order to serve high-standard structural and mechanical component applications, carboxyl terminated nitrile rubber (CTBN) - amine terminated polyetherimide(ATPEI) ? CTBN triblock copolymer (ABA type) as an functionalized thermoplastic was introduced. In this study, the cure kinetics of an epoxy system containing the diglycidyl ether of bisphenol A (DGEBA) and nadic methyl anhydride (NMA) as a curing agent, and their blends with ABA triblock copolymer at 20wt% were studied. Also, In the curing process, two major reactions were observed and identified by using a multi-autocatalytic model equation for the cure kinetics. The co-continuous phase can be obtained in the range of high contents of ABA triblock copolymer(20wt% and 30wt%) at 120℃. |
저자 | 김민영, 이정훈, 황승철, 김원호 |
소속 | 부산대 |
키워드 | cure kinetics;phase separation;epoxy |
원문파일 | 초록 보기 |