화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 콜로이드 및 분자조립 부문위원회 I
제목 Self-assembly of icosahedral cluster and its photonic properties
초록 Icosahedral colloidal clusters are a new class of spherical colloidal crystals. However, the optical characterization of the icosahedral cluster has not been achieved. Here, we produce icosahedral clusters by slowly shrinking particle-laden water droplets in water-saturated oil and characterize their optical properties. We controlled the drying time of aqueous droplets using a water-saturated hexadecane medium for preparation of the icosahedral cluster. In particular, we present real-time clustering using dual dye labeling under fluorescent confocal microscopy. The icosahedral clusters exhibit relatively strong structural colors compared to conventional onion-like supraballs. Simulations prove that the crystalline array inside the icosahedral cluster strengthens the collective specular diffraction. Moreover, the carbon-coated clusters further improve the saturation of structural colors.
저자 김철호1, 박상혁2, 김신현2, 이원보3, 문준혁1
소속 1서강대, 2KAIST, 3서울대
키워드 colloidal assembly; supraballs; icosahedral clusters; real-time observation; structural colors
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