화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.2018
발표분야 재료
제목 The role of shell thickness of quanutm dots to Performance of Light-Emitting Devices Based on Type-I Core/Shell Heterostructure
초록 The structure of quantum dots(QDs) is the keypoint which determines the performance of quantum dot light emitting devices. Here, we synthesized core/shell heterostructureCdSe/Zn1-XCdXS QDs with different shell thicknesses and tested the QDs in electroluminescent device. Accroding to spectroscopic analysis, the non-radiative decay pathways in QDs (e.g. energy transfer, charging and non-radiative Auger recombination) are attenuated while the shell thickness increase. As a consequence of attenuation, the device efficiency and the efficiency roll-off characteristics on high current densities are enhanced. The devices contained CdSe/Zn1-XCdXS with the thickest shell (core radius: 2 nm, total size: 8.3 nm) presenthigher device efficiency (peak E.Q.E. ~ 7.4 %) and brightness(Max luminance > 100,000 cd/m2) than thin shell one (core radius: 2nm,  total size: 4.5 nm).
저자 정병국1, 배완기2, 이도창1
소속 1한국과학기술원, 2KIST
키워드 Nanocrystal quantum dots; type-I heterostructures; light-emitting devices; energy transfer; charging; Auger recombination; efficiency roll-off
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