| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 봄 (05/12 ~ 05/14, 부산 벡스코(BEXCO)) |
| 권호 |
25권 1호 |
| 발표분야 |
포스터-환경·에너지 |
| 제목 |
Effect of Hydrophilic defect induced UIO-66 in dehydration performance |
| 초록 |
Polymer membranes often display trade-off effects between flux and selectivity in pervaporation (PV) therefore exploring the strategies for breaking the effects is crucial. In this study, hydrophilic defect induced with different size UIO-66 particle were engineered and blended into poly (vinyl alcohol) matrix to fabricate water-selective membrane for isopropyl alcohol (IPA) dehydration via PV technology. Hydrophilic Defect in UIO-66 was formed by making a missing link between ligand and metal cluster. As a result, UIO-66 with small size, had a highest defect density compared to large and medium size, hence uniformly distributed small size UIO-66 MMM showed strong interaction with water and enhanced the sorption as well as smooth diffusion through the tuned pore was enough to break trade-off effect. In the PV out put; small sized UIO-66 with 4% loading PVA MMM showed 11.6% and 22.8% increased of flux and separation factor respectively with that of compared to virgin PVA membrane. |
| 저자 |
신현태, 정호진, 최승용, chaudhari shivshankar subhash, 조계용, 문명준, 손민영
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| 소속 |
부경대 |
| 키워드 |
UIO-66; Defects; Mixed matrix membrane; polyvinyl alcohol; pervaporation
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| E-Mail |
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