| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO)) |
| 권호 |
25권 2호 |
| 발표분야 |
포스터-정밀화학 |
| 제목 |
Aluminum amide-mediated synthesis of 5-amino substituted 1,2,4-oxadiazole from 5-alkoxy-1,2,4-oxadiazole |
| 초록 |
So far, we have studied a novel conversion reaction that is simple and has a very high application range using the aluminum amide reagent. As with general organometallics, in the case of aluminum amide, carbon or nitrogen becomes nucleophilic due to Al-N polarization. Furthermore, lewis acidic aluminum has characteristic reactivity that is distinct from other organometallic reactants by electrophilic the substrate in the coordination of oxygen or nitrogen. In this study, we will develop a reaction using aluminum amide reagent to replace the alkoxy group of 5-alkoxy-1,2,4-oxadiazole. |
| 저자 |
Amarbayasgalan Nergui, 이상협
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| 소속 |
대구가톨릭대 |
| 키워드 |
Trimethylaluminum; aluminum amide; oxadiazole
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| E-Mail |
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