화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 41권 1호
발표분야 고분자가공/복합재료
제목 Thermal conductivity of liquid crystalline epoxy/boron nitride composites using non‐covalent functionalized boron nitride
초록 Non-covalent functionalization was used to functionalize boron nitride(f-BN) through π–π stacking of pyrene molecules , which results in improvement in the thermal conductivity of composites. Diglycidyl ether of bisphenol(BP) was synthesized for improving the crystallinity of epoxy composites, and thermal properties of BP/f-BN composites were compared with commercial biphenyl type epoxy composites. The thermal conductivity of BP composites were higher than commercial epoxy composites due to the π-π stacking of introduced mesogenic groups. The infrared (IR) and nuclear magnetic resonance (NMR) were used for characterization of synthesized BP resin. The curing temperature with different curing agents of epoxy was examined using differential scanning calorimetry (DSC). To analyze relationship between crystallinity and thermal conductivity, morphologies were observed by transmittance electron microscope (TEM) and thermal diffusivity was measured with the laser flash method.
저자 한세진, 윤호규, 서흔영, 염용식
소속 고려대
키워드 liquid crystalline epoxy; boron nitride; thermal conductivity; epoxy composites
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