| 학회 | 한국고분자학회 |
| 학술대회 | 2004년 가을 (10/08 ~ 10/09, 경북대학교) |
| 권호 | 29권 2호, p.513 |
| 발표분야 | 고분자 구조 및 물성 |
| 제목 | Formation and Characterization of Layered Structure from Polyimides Having Flexible Side Chains(Ⅱ) |
| 초록 | In our previous work, a series of polyimides having flexible side chains are designed and synthesized, which are composed of hydrophobic segment of long chains. As a result, we have shown that the polyimide with flexible alkyl side chains have a loose layered structures in the form of double stacking. In this work, we have synthesized homo-polyimides, co-polyimides and polyimide blends having hydrophobic and hydrophilic flexible side chains through chemical imidization of precursor poly(amic acid)s. Copolymers had amphiphilic character by virtue of incorporation of both hydrophilic and hydrophobic repeat unit. These copolymers were characterized by NMR and SAXS for the composition and structural analysis respectively1,2. We confirmed the linear dependency of molar volume and molar refraction through the calculation. Fig. 1. WAXD patterns for homo-polyimides Fig. 2. WAXD patterns for co-polyimides Reference 1. H. R. Kricheldorf and A. Domschke, Macromolecules., 29, 1337 (1996) 2. M. Ballauff, Rapid Commun., Makromol. Chem., 7, 407 (1986) |
| 저자 | 한승산1, 이미혜1, 최길영1, 임승순2, 김용석1 |
| 소속 | 1한국화학(연), 2한양대 |
| 키워드 | polyimide; molar volume; molar refraction |
