화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2018년 봄 (04/25 ~ 04/27, 창원컨벤션센터)
권호 24권 1호, p.547
발표분야 에너지 환경
제목 Pt cathode facilitates direct reduction of NO along with mediated reduction at electro-scrubbing process
초록 Inspired by direct reduction of NO by polycrystalline and Pt (111) phase cathodes to N2O and NH3 formation, use of Pt cathode could be beneficial for enhanced reduction of NO with combination of mediated electrochemical reduction (MER) and direct electrochemical reduction (DER) processes instead of only MER. This work presents, a lab scale 50 and 400 cm2 working electrode area contained divided electrochemical cell was developed and used to generate [NiI(CN)4]3- in 10 M KOH using polycrystalline Pt cathode with capacity of 0.6 to 2 L scrubbing solution (catholyte). The electrogenerated [NiI(CN)4]3- was concurrently scrubbed the feed gas NO at electroscrubbing. This NO reduction process was characterized and monitored by real time FTIR gas analyser.  

Keywords: NO reduction, NH3 formation, MER, DER, Electro-scrubbing  
저자 문일식, A.G.Ramu, G.Muthuraman
소속 순천대
키워드 에너지 환경
E-Mail ismoon@sunchon.ac.kr
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