| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Control of Crystallinity via Terpolymer Approach in Diketopyrrolopyrrole-Based Polymers Semiconductors |
| 초록 |
Tuning crystalline properties of polymers has been proven to boost electrical performance in conjugated polymers. Herein, a new series of conjugated random terpolymers was synthesized from an electron-deficient diketopyrrolopyrrole-based unit in conjugation with two electron-rich selenophene and thiophene species. The crystallinity of the terpolymers could be systematically controlled by tuning the ratio between the two species. An increase in selenophene content induced a remarkable enhancement in crystallinity of the terpolymers. These changes in the crystalline properties of polymers had a dramatic effect on the performances of organic field-effect transistors. The investigation of control of crystallinity via terpolymer approach in this work can provide new insight into the molecular design of high-performance polymer semiconductors. |
| 저자 |
송인호1, 김기현2, 박선희2, 유호정3, 강현범2, 김범준2, 오준학1, Xiaobo Shang1
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| 소속 |
1포항공과대, 2한국과학기술원, 3울산과학기술대 |
| 키워드 |
diketopyrrolopyrroles; organic thin-film transistors
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| E-Mail |
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