| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Influence of Thin-Film Crystallinity in Electrical Properties of Diketopyrrolopyrrole-Based Terpolymers |
| 초록 |
Tuning crystalline properties of polymers has been proven to boost electrical performance in conjugated polymers. Herein, a new series of conjugated random terpolymers was synthesized from an electron-deficient diketopyrrolopyrrole-based unit in conjugation with two electron-rich selenophene and thiophene species. The crystallinity of the terpolymers could be systematically controlled by tuning the ratio between the two species. An increase in selenophene content induced a remarkable enhancement in crystallinity of the terpolymers. These changes in the crystalline properties of polymers had a dramatic effect on the performances of organic field-effect transistors. The investigation of control of crystallinity via terpolymer approach in this work can provide new insight into the molecular design of high-performance polymer semiconductors. |
| 저자 |
김기현1, 박선희1, 강현범1, 김범준1, 유호정2, 오준학3, 송인호3
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| 소속 |
1한국과학기술원, 2울산과학기술대, 3포항공과대 |
| 키워드 |
diketopyrrolopyrroles; organic thin-film transistors
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| E-Mail |
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