화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 분자전자 부문위원회
제목 Rhenium oxide as an efficient p-dopant to overcome S-shaped current density-voltage curves in organic photovoltaics with a deep highest occupied molecular orbital level donor layer
초록 Effect of p-dopants in a p-doped hole transport layer inserted between indium tin oxide and a donor layer of α,α’-bis(2,2-dicyanovinyl)-quinquethiophene with a deep highest occupied molecular orbital level is reported to remove the S-shape in the organic photovoltaics (OPV) cell. Among the p-dopants of ReO3, MoO3, WO3 and CuI, ReO3 possesses the largest work function and turns out to be the most efficient p-dopant to remove the S-shape of the current density-voltage curve in the OPV cells. The rest of the dopants could not get rid of the S-shape, even with a doping concentration of 25 mol%. The difference among the dopants can be understood by the different charge generation efficiency of the dopants.
저자 김대호1, 김장주1, 김태민1, 정원익2
소속 1서울대, 2LG화학
키워드 Organic solar cell; donor; Open circuit voltage; S-curve; Hole transport layer; Doping
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