화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 고분자합성-구조제어중합
제목 E-Beam Synthesis of Organic-Inorganic Hybrid Materials for the Reduction of the Excimer Formation in Polyfluorenes.
초록 To reduce the aggregate or excimer formation in light-emitting poly(di-n-didodecylfluorene)s (PF) during annealing at high temperatures, organic-inorganic hybrid materials of 2,7-dibromo-9,9-didodecyl-fluorene were synthesized by non-hydrolytic sol-gel reaction. After synthesis, the E-beam process of the unreacted C=C bonds of 3-(trimethoxysilyl)propylmethacrylate (ATMS) was performed using 2,2-dimethoxy-2-phenyl-acetophenone as an initiator. The concentration of the photoinitiator was 2 mol % of the total C=C bonds in ATMS. The photoluminescence spectra of these materials were measured during annealing at high temperature.
저자 노승주, 권용구, 김성은, 허성익, 석민균
소속 인하대
키워드 E-beam; hybrid material; polyfluorene; excimer
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