화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2014년 가을 (11/12 ~ 11/14, 엑스코(대구))
권호 18권 2호
발표분야 고분자-포스터
제목 Improved anti-oxidation properties of Lyocell fiber achieved by phosphorus compound
초록 The anti-oxidation behavior of Lyocell fibers during flame-retardant treatment as a function of the effects of a phosphorus compound was explored. Di-ammonium-hydrogen phosphate (DAHP) was observed to reduce the thermal degradation rate of the Lyocell fibers and increase the char yield; DAHP also increased the limiting oxygen index via a first-order relationship with the char yield. The integral procedure decomposition temperature (IPDT) increased significantly, and the activation energy increased by a certain factor, indicating a slow degradation pathway involving dehydration, rearrangement, formation of carbonyl groups, evolution of carbon monoxide and carbon dioxide, and formation of a carbonaceous residue for the flame retardancy of Lyocell fibers.
저자 배병철1, 김은애1, 전영표1, 이철위1, 인세진2, 이영석3, 임지선1
소속 1한국화학(연), 2우송대, 3충남대
키워드 Lyocell; Flame retardant; Thermogravimetric analysis; Phosphorus compound
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