학회 |
한국공업화학회 |
학술대회 |
2014년 가을 (11/12 ~ 11/14, 엑스코(대구)) |
권호 |
18권 2호 |
발표분야 |
고분자-포스터 |
제목 |
Improved anti-oxidation properties of Lyocell fiber achieved by phosphorus compound |
초록 |
The anti-oxidation behavior of Lyocell fibers during flame-retardant treatment as a function of the effects of a phosphorus compound was explored. Di-ammonium-hydrogen phosphate (DAHP) was observed to reduce the thermal degradation rate of the Lyocell fibers and increase the char yield; DAHP also increased the limiting oxygen index via a first-order relationship with the char yield. The integral procedure decomposition temperature (IPDT) increased significantly, and the activation energy increased by a certain factor, indicating a slow degradation pathway involving dehydration, rearrangement, formation of carbonyl groups, evolution of carbon monoxide and carbon dioxide, and formation of a carbonaceous residue for the flame retardancy of Lyocell fibers. |
저자 |
배병철1, 김은애1, 전영표1, 이철위1, 인세진2, 이영석3, 임지선1
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소속 |
1한국화학(연), 2우송대, 3충남대 |
키워드 |
Lyocell; Flame retardant; Thermogravimetric analysis; Phosphorus compound
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E-Mail |
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