화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO))
권호 25권 2호
발표분야 포스터-에너지저장·변환
제목 Unveiling Trifunctional Active Sites of Heteronanosheet Electrocatalyst for Highly Efficient Integrated Cascade Battery/Electrolyzer Systems
초록 We identify the unique trifunctional active sites of ReS2 and NiFe layered double hydroxide (NiFe-LDH) heteronanosheets (ReS2/NiFe-LDH) for integrated cascade Zn-air battery/electrolyzer systems. Along with the edge and surface sites of NiFe-LDH for both oxygen evolution reaction and oxygen reduction reaction activities, the unprecedented activity of the ReS2/NiFe-LDH heteronanosheets for hydrogen evolution reaction is emerged from the S-O bonds at the heterointerfaces, in coupled with the strong coupling effect and vertical alignment of NiFe-LDH and ReS2. The outstanding trifunctional activities and the mechanism understanding ensure the use of ReS2/NiFe-LDH heteronanosheets for the development of integrated cascade battery/electrolyzer systems, showing great promising for the cost-effective energy storage and H2 production applications ranging from the distributed households to the assembly for electrical vehicles.
저자 HAN XIAOTONG, 박호석
소속 성균관대
키워드 Trifunctional electrocatalyst; Integrated cascade system; Heteronanosheets; DFT calculation; Zn-air battery; Water electrolysis
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