화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 41권 1호
발표분야 분자전자 부문위원회 I
제목 Molecular ordering enhancement in semiconducting polymer assisted by crystals of conjugated organic molecules  
초록 Organic field-effect transistors (OFETs) based on solution processable semiconducting polymers have received much attention for applications in printed organic electronics. In recent years, electrical performance in polymer semiconductors has improved owing to synthesis of novel materials and processing techniques. In particular, the field-effect mobility is sensitively influenced by the molecular arrangement and crystallinity in thin semiconducting film. Here we investigate the packing structure of blending electron-transporting polymer and small molecules. The blends of polymer and small molecules order in a cofacial arrangement where charge transfer is highly efficient in the solid state. These structural changes, as a function of blend composition, suggest a model for the microstructure where the location of the small organic species are incorporated rather than randomly dispersed.
저자 강민지1, 여준석2, 박원태3, 황한수1, 김남구1, 임대희1, 노용영3, 김동유1
소속 1광주과학기술원, 2한국과학기술(연), 3동국대
키워드 Organic field-effect transistor; molecular arrangement
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